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1,3,5‐Triphenyl‐2,4,6‐trimesityl‐1,3,5,2,4,6‐triphosphatriborinane: A 6π‐Electron Heteroaromatic Ligand
Author(s) -
Kaufmann Bernhard,
Metzler Nils,
Nöth Heinrich,
Paine Robert T.
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270506
Subject(s) - chemistry , moiety , chromium , ring (chemistry) , ligand (biochemistry) , metal , stereochemistry , medicinal chemistry , electron , crystallography , organic chemistry , receptor , biochemistry , physics , quantum mechanics
The preparation of tricarbonyl(η 6 ‐1,3,5‐triphenyl‐2,4,6‐trimesityl‐1,3,5,2,4,6‐triphosphatriane)chromium ( 4 ) is reported. Its X‐ray structure reveals an orientation of the Cr(CO) 3 moiety with respect to the almost planar B 3 P 3 ring typical of an arene metal tricarbonyl complex.