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Flüchtige Metallalkoxide nach dem Konzept der donorfunktionalisierten Liganden
Author(s) -
Herrmann Wolfgang A.,
Huber Norbert W.
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270505
Subject(s) - chemistry , homoleptic , alkoxide , manganese , cobalt , polymer chemistry , monomer , metal , zinc , ether , stereochemistry , inorganic chemistry , organic chemistry , catalysis , polymer
Volatile Metal Alkoxides According to the Concept of Donor‐Functionalized Ligands Homoleptic metal(II) alkoxides 3–5 of manganese, iron, cobalt, and zinc are prepared by applying the concept of donor‐functionalized ligands. The trifunctional ether ligands 1 thus form volatile metal alkoxides that sublime below 100°C at 10 −2 mbar. Monomeric molecules are present in the gas phase and are likely to occur in the solid state, too. The heterodimetallic alkoxide 6 (Li/Co) sublimes without decomposition.