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Synthesis and Structural Characterization of the Bent Nitrosyl Organometallic Complex [NBu 4 ][Pt(C 6 Cl 5 ) 2 Cl 2 (NO)]
Author(s) -
Forniés Juan,
Menjón Babil,
SanzCarrillo Rosa María,
Tomás Milagros
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270412
Subject(s) - chemistry , crystallography , platinum , bent molecular geometry , tetragonal crystal system , stereochemistry , ligand (biochemistry) , basal plane , atom (system on chip) , x ray crystallography , yield (engineering) , crystal structure , catalysis , diffraction , biochemistry , physics , receptor , materials science , organic chemistry , computer science , optics , embedded system , metallurgy
The title complex has been prepared in 36% yield by reaction of [NBu 4 ] 2 [ trans ‐Pt(C 6 Cl 5 ) 2 Cl 2 ] with NOClO 4 (1: 1 ) in CH 2 Cl 2 . The anion exhibits an almost tetragonal‐pyramidal geometry (X‐ray analysis), the platinum atom being virtually located in the basal plane and the NO ligand occupying the apical position. The PtNO unit is bent [119.5(8)°].