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Funktionalisierung von C 60 mit Nitriloxiden zu 4,5‐Dihydroisoxazolen und deren Strukturbestimmung
Author(s) -
Irngartinger Hermann,
Köhler ClausMarkus,
HuberPatz Ursula,
Krätschmer Wolfgang
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270318
Subject(s) - nitrile , chemistry , high resolution , derivative (finance) , mass spectrometry , nuclear magnetic resonance spectroscopy , stereochemistry , polymer chemistry , crystallography , organic chemistry , remote sensing , chromatography , financial economics , economics , geology
Functionalization of C 60 with Nitrile Oxides to 4,5‐Dihydroisoxazoles and Their Structure Determination Cycloadducts 3 of nitrile oxides 2 with C 60 ( 1 ) are synthesized and isolated. The cycloadducts are characterized by 13 C‐NMR spectroscopy and high‐resolution FAB mass spectrometry. X‐ray structure determination of the 3‐(9‐anthryl)‐4,5‐dihydroisoxazole derivative 3a of C 60 with CS 2 included in the crystals is achieved at 173 K without disorder problems.