Funktionalisierung von C 60  mit Nitriloxiden zu 4,5‐Dihydroisoxazolen und deren Strukturbestimmung | Zendy

Irngartinger Hermann | Zendy; Köhler ClausMarkus | Zendy; HuberPatz Ursula | Zendy; Krätschmer Wolfgang | Zendy

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Funktionalisierung von C 60 mit Nitriloxiden zu 4,5‐Dihydroisoxazolen und deren Strukturbestimmung

Author(s) -

Irngartinger Hermann,

Köhler ClausMarkus,

HuberPatz Ursula,

Krätschmer Wolfgang

Publication year - 1994

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19941270318

Subject(s) - nitrile , chemistry , high resolution , derivative (finance) , mass spectrometry , nuclear magnetic resonance spectroscopy , stereochemistry , polymer chemistry , crystallography , organic chemistry , remote sensing , chromatography , financial economics , economics , geology

Functionalization of C 60 with Nitrile Oxides to 4,5‐Dihydroisoxazoles and Their Structure Determination Cycloadducts 3 of nitrile oxides 2 with C 60 ( 1 ) are synthesized and isolated. The cycloadducts are characterized by 13 C‐NMR spectroscopy and high‐resolution FAB mass spectrometry. X‐ray structure determination of the 3‐(9‐anthryl)‐4,5‐dihydroisoxazole derivative 3a of C 60 with CS 2 included in the crystals is achieved at 173 K without disorder problems.

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