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Synthesis and Characterization of Phthalocyanines Containing Four 14‐Membered Tetraaza Macrocycles
Author(s) -
Koçak Makbule,
Güek Ayşegül,
Gül Ahmet,
Bekaroǧlu Özer
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270212
Subject(s) - chemistry , metal , phthalocyanine , copper , tosyl , characterization (materials science) , polymer chemistry , metal ions in aqueous solution , ion , stereochemistry , organic chemistry , nanotechnology , materials science
Metal phthalocyanines (M = Cu, Ni, Co, SnCl 2 ) 3–6 containing four 14‐membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni 2+ ions giving a pentanuclear complex which is extremely soluble in polar solvents. The mass spectrum of the [hexadecakis( N‐p ‐tosyl)‐tetrakis‐macrocycle‐phthalocyaninato]copper(II) 3 is described