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Synthesis of Platinum(II) Alkane‐ and Arenethiosulfinato Complexes — Crystal Structure Analysis of N ‐[(Benzylsulfinyl)thio]phthalimide
Author(s) -
Weigand Wolfgang,
Wünsch Ralf,
Robl Chrtian,
Amreinb Walter
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270116
Subject(s) - chemistry , phthalimide , thio , platinum , crystal structure , medicinal chemistry , phthalimides , stereochemistry , alkane , oxidative addition , crystallography , organic chemistry , hydrocarbon , catalysis
Abstract The oxidative addition of N ‐[(alkyl‐ and arylsulfinyl)thio]‐phthalimides 3a–d to Pt(PPh 3 ) 2 (C 2 H 4 ) gives the platinum(II) thiosulfinato complexes cis ‐Pt[(S‐S(O)‐R)(Nphth)(PPh 3 )2] 4a–d ; the structure of N ‐[(benzylsulfinyl)thio]phthalimide ( 3c ) has been characterized by X‐ray crystallography.