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Reaktion von Decaboran mit dem Phosphaalkin PC t Bu
Author(s) -
Meyer Franc,
Pactzold Peter,
Englert Ulli
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270115
Subject(s) - chemistry , decaborane , stereochemistry , borane , crystallography , medicinal chemistry , boron , catalysis , organic chemistry
Reaction of Decaborane with the Phosphaalkyne PC t Bu The borane B 10 H 12 (SMe 2 )2 ( 1 ) reacts with the phosphaalkyne P°C t Bu to form the product [B 10 H 11 (SMe 2 )][C( t Bu)‐PH](B 10 H 12 ) ( 2 ), in which two B 10 units are linked by a HP‐C t Bu bridge. The B 10 unit B is simply bound to the bridge C atom, whereas the B 10 unit A is bound to both bridging atoms, P and C, by atom B6 and, moreover, to the P atom by atom B5. The solvate complex 2 · CH 2 Cl 2 crystallizes in the space group P ¯.