Soluble (Phthalocyaninato)ruthenium(II) Phosphane Complexes | Zendy

Bulatov Alexander | Zendy; Knecht Siegfried | Zendy; Subramanian L. R. | Zendy; Hanack Michael | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Soluble (Phthalocyaninato)ruthenium(II) Phosphane Complexes

Author(s) -

Bulatov Alexander,

Knecht Siegfried,

Subramanian L. R.,

Hanack Michael

Publication year - 1993

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19931261136

Subject(s) - chemistry , phthalonitrile , ruthenium , phthalocyanine , medicinal chemistry , proton nmr , polymer chemistry , stereochemistry , organic chemistry , catalysis

Hitherto unknown ruthenium phthalocyanine complexes with phosphane ligands – PcRu(PEt 2 Ph) 2 ( 1 ) and PcRu(PPh 3 ) 2 ( 2 ) – soluble in common organic solvents were prepared. Two methods were used for their synthesis: 1) Reaction of phthalonitrile with [Ru 2 Cl 3 (PEt 2 Ph) 6 ]Cl in n ‐pentanol in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) and 2) reaction of PcRu with the corresponding phosphanes. The products 1 and 2 were characterized by their IR, UV/Vis, FD‐MS, and 1 H‐NMR data.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research