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Soluble (Phthalocyaninato)ruthenium(II) Phosphane Complexes
Author(s) -
Bulatov Alexander,
Knecht Siegfried,
Subramanian L. R.,
Hanack Michael
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931261136
Subject(s) - chemistry , phthalonitrile , ruthenium , phthalocyanine , medicinal chemistry , proton nmr , polymer chemistry , stereochemistry , organic chemistry , catalysis
Hitherto unknown ruthenium phthalocyanine complexes with phosphane ligands – PcRu(PEt 2 Ph) 2 ( 1 ) and PcRu(PPh 3 ) 2 ( 2 ) – soluble in common organic solvents were prepared. Two methods were used for their synthesis: 1) Reaction of phthalonitrile with [Ru 2 Cl 3 (PEt 2 Ph) 6 ]Cl in n ‐pentanol in the presence of 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) and 2) reaction of PcRu with the corresponding phosphanes. The products 1 and 2 were characterized by their IR, UV/Vis, FD‐MS, and 1 H‐NMR data.