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A Soluble Benzodifluoranthene Derivative by Dehydration of an Oxygen‐Bridged Precursor
Author(s) -
Schirmer Heike,
Schlüter ArnulfDieter,
Enkelmann Volker
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931261132
Subject(s) - chemistry , dehydration , alkyl , derivative (finance) , crystal structure , dehydration reaction , characterization (materials science) , stereochemistry , organic chemistry , biochemistry , nanotechnology , materials science , financial economics , economics
Synthesis and characterization of the alkyl chain‐substituted benzodifluoranthene 6 are described. The final synthetic step involves an acid‐promoted dehydration whose conversion is determined to be quantitative. The solubilities of compounds 4e, 5 , and 6 are qualitatively correlated with structural features. The molecular structure of 6 in the crystal is elucidated by an X‐ray structure analysis.