Premium
Bis[(di‐ tert ‐butylphosphanyl)methyl]methylphosphan
Author(s) -
Krill Jochen,
Shevchenko Igor V.,
Fischer Axel,
Jones Peter G.,
Schmutzler Reinhard
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931261105
Subject(s) - chemistry , sulfur , dimethyl sulfide , molybdenum , denticity , yield (engineering) , medicinal chemistry , crystal structure , sulfide , stereochemistry , organic chemistry , materials science , metallurgy
Bis[(di‐ tert ‐butylphosphanyl)methyl]methylphosphane [1] The synthesis of [(di‐ tert ‐butylphosphanyl)methyl]dimethyl‐phosphane ( 3 ) and of the title compound 5 is described. 5 reacts with sulfur to form the trisulfide 6 . Both 3 and 5 behave as bidentate ligands in forming the molybdenum complexes 8 and 10 , which are characterized by single crystal X‐ray structure determinations. 10 reacts with sulfur to yield the sulfide 11 , which decomposes in solution within 6 h.