Bis[(di‐ tert ‐butylphosphanyl)methyl]methylphosphan | Zendy

Krill Jochen | Zendy; Shevchenko Igor V. | Zendy; Fischer Axel | Zendy; Jones Peter G. | Zendy; Schmutzler Reinhard | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Bis[(di‐ tert ‐butylphosphanyl)methyl]methylphosphan

Author(s) -

Krill Jochen,

Shevchenko Igor V.,

Fischer Axel,

Jones Peter G.,

Schmutzler Reinhard

Publication year - 1993

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19931261105

Subject(s) - chemistry , sulfur , dimethyl sulfide , molybdenum , denticity , yield (engineering) , medicinal chemistry , crystal structure , sulfide , stereochemistry , organic chemistry , materials science , metallurgy

Bis[(di‐ tert ‐butylphosphanyl)methyl]methylphosphane [1] The synthesis of [(di‐ tert ‐butylphosphanyl)methyl]dimethyl‐phosphane ( 3 ) and of the title compound 5 is described. 5 reacts with sulfur to form the trisulfide 6 . Both 3 and 5 behave as bidentate ligands in forming the molybdenum complexes 8 and 10 , which are characterized by single crystal X‐ray structure determinations. 10 reacts with sulfur to yield the sulfide 11 , which decomposes in solution within 6 h.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research