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Cyclopropanierung von Fullerenen
Author(s) -
Bingel Carsten
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931260829
Subject(s) - fullerene , chemistry , intramolecular force , tandem , fullerene chemistry , halogen , stereochemistry , polymer chemistry , organic chemistry , materials science , alkyl , composite material
Cyclopropylation of Fullerenes Cyclopropylation of fullerenes C 60 and C 70 is achieved by a tandem process. Michael addition of a stabilized α‐halocarbanion to fullerenes followed by intramolecular substitution of the halogen yields fullerene derivatives with functional groups.