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Preparation of Benzo‐diimidazoles and Benzo‐triimidazoles
Author(s) -
Mataka Shuntaro,
Irie Takashi,
Ikezaki Youji,
Tashiro Masashi
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931260811
Subject(s) - chemistry , tetramine , benzene , medicinal chemistry , isocyanate , pyrolysis , aryl , organic chemistry , polyurethane , alkyl
The reaction of benzenehexamine ( 1 ), benzene‐1,2,3,4‐tetramine ( 4 ), and benzene‐1,2,4,5‐tetramine ( 6 ) with aryl isocyanate 2 afforded the corresponding hexakis( N '‐arylureido)benzene 3 and the tetrakis( N '‐arylureido)benzenes 5 and 7 . Pyrolysis of 3, 5 , and 7 at 400°C furnished the benzo‐triimidazoletrione 8 and benzo‐biimidazolediones 10 and 11 .