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Thioalkylierung der Metall–Kohlenstoff‐Mehrfachbindung in Carbin‐ und Carben‐Komplexen von Molybdän und Wolfram
Author(s) -
Kreißl Fritz R.,
Schütt Wolfgang,
Stegmair Claudia M.,
Ullrich Norbert,
Keller Hans,
Ostermeier Josef,
Herdtweck Eberhardt
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931260717
Subject(s) - carbyne , chemistry , molybdenum , carbene , sulfonium , tungsten , tetrafluoroborate , trimethylphosphine , metal , polymer chemistry , molecule , inorganic chemistry , organic chemistry , catalysis , salt (chemistry) , ionic liquid
Thiomethylation of the Metal–Carbon Multiple Bond of Carbyne and Carbene Complexes of Molybdenum and Tungsten Carbyne complexes of molybdenum and tungsten react with dialkyl(methylthio)sulfonium tetrafluoroborate in a stepwise addition of the alkylthio cation to the metal–carbon multiple bond yielding dicationic η 3 ‐dithiomethyl complexes.