Thioalkylierung der Metall–Kohlenstoff‐Mehrfachbindung in Carbin‐ und Carben‐Komplexen von Molybdän und Wolfram | Zendy

Kreißl Fritz R. | Zendy; Schütt Wolfgang | Zendy; Stegmair Claudia M. | Zendy; Ullrich Norbert | Zendy; Keller Hans | Zendy; Ostermeier Josef | Zendy; Herdtweck Eberhardt | Zendy

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Thioalkylierung der Metall–Kohlenstoff‐Mehrfachbindung in Carbin‐ und Carben‐Komplexen von Molybdän und Wolfram

Author(s) -

Kreißl Fritz R.,

Schütt Wolfgang,

Stegmair Claudia M.,

Ullrich Norbert,

Keller Hans,

Ostermeier Josef,

Herdtweck Eberhardt

Publication year - 1993

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19931260717

Subject(s) - carbyne , chemistry , molybdenum , carbene , sulfonium , tungsten , tetrafluoroborate , trimethylphosphine , metal , polymer chemistry , molecule , inorganic chemistry , organic chemistry , catalysis , salt (chemistry) , ionic liquid

Thiomethylation of the Metal–Carbon Multiple Bond of Carbyne and Carbene Complexes of Molybdenum and Tungsten Carbyne complexes of molybdenum and tungsten react with dialkyl(methylthio)sulfonium tetrafluoroborate in a stepwise addition of the alkylthio cation to the metal–carbon multiple bond yielding dicationic η 3 ‐dithiomethyl complexes.

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