Syntheses and Structures of Transition‐Metal Complexes of Mesoionic Olate, Thiolate, Selenolate, and Cyclopentadienide | Zendy

Araki Shuki | Zendy; Butsugan Yasuo | Zendy

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Syntheses and Structures of Transition‐Metal Complexes of Mesoionic Olate, Thiolate, Selenolate, and Cyclopentadienide

Author(s) -

Araki Shuki,

Butsugan Yasuo

Publication year - 1993

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19931260515

Subject(s) - mesoionic , chemistry , molybdenum , transition metal , cyclopentadienyl complex , metal , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , catalysis

The dicarbonyl(η1‐cyclopentadienyl)iron(II) complex 5 of 1,3‐diphenyltetrazolium‐5‐olate ( 4 ) and the pentacarbonylmolybdenum(0) complexes 7, 11 , and 9 of 1,3‐diphenyltetrazolium‐5‐thiolate ( 6 ), −5‐selenolate ( 10 ), and 5‐methyl‐1,4‐diphenyl‐1,2,4‐triazolium‐3‐thiolate ( 8 ) as well as tricarbonylchromium(0) complex 13 and ‐molybdenum(0) complex 14 of 1,3‐diphenyltetrazolium‐5‐cyclopentadienide ( 12 ) have been prepared. Their physicochemical properties are discussed on the basis of spectroscopic properties.

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