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Neue Beiträge zur Chemie des Mangans: Synthese und Strukturen zweier monomerer Mn II 1‐Verbindungen und eines hexanuklearen Mn II/III 1‐Komplexes
Author(s) -
Köhler Katrin,
Roesky Herbert W.,
Noltemeyer Mathias,
Schmidt HansGeorg,
FreireErdbrügger Cristina,
Sheldrick George M.
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931260411
Subject(s) - chemistry , manganese , crystal structure , valence (chemistry) , crystallography , x ray crystallography , monomer , stereochemistry , medicinal chemistry , physics , organic chemistry , diffraction , optics , polymer
New Contributions to the Chemistry of Manganese: Syntheses and Structures of two Monomeric Mn II Compounds and a Hexanuclear Mn II/III Complex Two novel mononuclear manganese(II) complexes, Mn[OSi(O t Bu) 3 ] 2 ·(Py) 3 ( 2 ) and Mn[PhC 6 H 4 C(NSiMe 3 ) 2 ] 2 ·THF ( 3 ), and a hexanuclear mixed‐valence manganese(II/III) complex Mn 6 O 2 (O 2 C t Bu) 10 ·(Py) 4 ( 5 ) have been prepared, and their structures have been determined by X‐ray crystal structure analyses.