The Stereochemistry of the Trinaphthyl‐Terrylene Conversion | Zendy

Anton Ute | Zendy; Adam Martin | Zendy; Wagner Manfred | Zendy; QiLin Zhou | Zendy; Müllen Klaus | Zendy

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The Stereochemistry of the Trinaphthyl‐Terrylene Conversion

Author(s) -

Anton Ute,

Adam Martin,

Wagner Manfred,

QiLin Zhou,

Müllen Klaus

Publication year - 1993

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19931260231

Subject(s) - chemistry , steric effects , reactivity (psychology) , naphthalene , alkylation , stereochemistry , alkyl , hydrocarbon , crystal structure , medicinal chemistry , crystallography , organic chemistry , catalysis , medicine , alternative medicine , pathology

Alkylated terrylenes can be synthesized by a twofold cyclization of an appropriately substituted trinaphthyl [1, 11] . In this paper, we consider a special case. The alkyl substitution in the starting material 1 strongly affects the interplanar angle between the naphthalene moieties. After cyclization, the substituents are positioned in the sterically crowded bay region of the title structure 2 . The influence of the steric strain on the reactivity of 1 and on the stability of the resulting hydrocarbon 2 is investigated. Special emphasis is placed on the crystal structures of 1 and 2 .

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