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Neue Beobachtungen zur Stereoselektivität von Monoiodcarben‐Additionen
Author(s) -
Dehmlow Eckehard V.,
Soufi Johanna,
Stammler HansGeorg,
Neumann Beate
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931260229
Subject(s) - chemistry , bicyclic molecule , stereoselectivity , stereochemistry , tricyclic , medicinal chemistry , organic chemistry , catalysis
New Observations Concerning the Stereoselectivity of Monoiodocarbene Additions Contrary to our earlier claim, CHI gives endo / exo isomer mixtures with cyclooctene. However, only endo 1‐iodo compounds 7, 8, 10–12 are obtained from COD and COT. Tricyclic compound 7 rearranges partially to bicyclic 9 , X‐ray structure determinations of 7 and 9 were performed.
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