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1‐Alkynyl Disulfides: Their Characterization and Their 1‐Thiapropargyl — 3‐Thiaallenyl Rearrangements
Author(s) -
Nørkjær Kim,
Senning Alexander
Publication year - 1993
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19931260113
Subject(s) - chemistry , sigmatropic reaction , characterization (materials science) , stereochemistry , medicinal chemistry , nanotechnology , materials science
The synthesis of novel 1‐alkynyl disulfides 1 is described together with their 1‐thiapropargyl — 3‐thiaallenyl rearrangement and a [1,3]‐sigmatropic shift of 1‐alkynyl amino disulfides, followed by rearrangement of the aminothio‐substituted thioketenes so formed.