Fluorenylindate: Verbindungen mit schwachen In — C‐Bindungen | Zendy

Neumüller Bernhard | Zendy

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Fluorenylindate: Verbindungen mit schwachen In — C‐Bindungen

Author(s) -

Neumüller Bernhard

Publication year - 1993

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19931260103

Subject(s) - chemistry , medicinal chemistry , lithium (medication) , crystal structure , ether , diethyl ether , yield (engineering) , stereochemistry , crystallography , organic chemistry , medicine , materials science , metallurgy , endocrinology

Fluorenylindates: Compounds with Weak In — C Bonds In diethyl ether, fluorenyllithium reacts with indium(III) chloride to yield a lithium tetrafluorenylindate ( 1 ). Recrystallisation from THF gives [Li(THF) 4 ][In(C 13 H 9 ) 4 ] ( 2 ). If the reaction is carried out in THF, the chlorotrifluorenylindate [Li(THF) 4 ]‐[ClIn(C 13 H 9 ) 3 ] ( 3 ) is isolated. According to crystal structure analyses 2 has long and weak In — C bonds [224.8(5) – 230.3(5) pm], while these distances in 3 are somewhat shorter [222.9 (5) – 226.7(4) pm].

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