On the Reactions of Fe(CH 2 ) +  with 1,7–Octadiene in the Gas Phase | Zendy

Stöckigt Detlef | Zendy; Schwarz Helmut | Zendy

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On the Reactions of Fe(CH 2 ) + with 1,7–Octadiene in the Gas Phase

Author(s) -

Stöckigt Detlef,

Schwarz Helmut

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921251231

Subject(s) - chemistry , gas phase , metathesis , chemical reaction , phase (matter) , inorganic chemistry , organic chemistry , polymerization , polymer

In contrast to the reactions of “bare” Fe + with 1,7–octadiene ( 1 ), the chemistry of Fe(CH 2 ) + with 1 represents a “textbook” example for a gas–phase metathesis process to generate in a clean fashion Fe(C 2 H 4 ) + . Similarly, for the formation of Fe(C 6 H 6 ) + a mechanism is suggested which is in keeping with the experimental findings. In contrast, the reactions of Fe(CH 2 ) + with 1 leading to Fe(C 3 H 4 ) + and Fe(C 4 H 6 ) + are so complex that a coherent description is not yet possible.

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