1,2‐Dihydro‐1,3,2λ 5 ,4λ 5 ‐diazadiphosphet – Synthese, Struktur und Isomerisierung zum „inneren Salz”︁ von 1,3,2,4λ 5 ‐Diazadiphosphetan‐2‐iumhydroxid * | Zendy

Böske Jürgen | Zendy; Niecke Edgar | Zendy; Krebs Bernt | Zendy; Läge Mechtild | Zendy; Henkel Gerald | Zendy

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1,2‐Dihydro‐1,3,2λ 5 ,4λ 5 ‐diazadiphosphet – Synthese, Struktur und Isomerisierung zum „inneren Salz”︁ von 1,3,2,4λ 5 ‐Diazadiphosphetan‐2‐iumhydroxid *

Author(s) -

Böske Jürgen,

Niecke Edgar,

Krebs Bernt,

Läge Mechtild,

Henkel Gerald

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921251202

Subject(s) - chemistry , phosphorane , isomerization , yield (engineering) , stereochemistry , medicinal chemistry , nuclear magnetic resonance spectroscopy , x ray crystallography , crystallography , catalysis , organic chemistry , materials science , metallurgy , physics , diffraction , optics

1,2‐Dihydro‐1,3,2λ 5 ,4λ 5 ‐diazadiphosphete – Synthesis, Structure and Isomerization to the „Inner Salt” of 1,3,2,4λ 5 ‐Diazadiphosphetan‐2‐ium Hydroxide The photochemical reaction of the azidophosphane ( i Pr 2 N) 2 PN 3 ( 1 ) with the tetraazaphospholene ( 3 ) and the bis(imino)phosphorane (Me 3 Si) 2 NP(NSiMe 3 ) 2 ( 6 ) proceeds by elimination of N 2 to yield ( 5 ) and by 1,3‐silyl group shift to furnish ( 8 ) the structures of which were determined by means of NMR data and, in the case of 5 , additionally by X‐ray structure analysis.

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