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Unsymmetrical phthalocyanines with a single macrocyclic substituent
Author(s) -
Musluoglu Emel,
Gürek Aysegül,
Ahsen Vefa,
Gül Ahmet,
Bekaroǧlu özer
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921251023
Subject(s) - chemistry , substituent , phthalonitrile , tetra , phthalocyanine , boron , 15 crown 5 , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , crown ether , ion
Unsymmetrical phthalocanines ( 5–7 ) with a single macrocyclic substituent are synthesized by the reaction of the boron complex of phthalonitrile ( 1 ) with the iminoisoindoline derivatives 2–4 of macrocyclic compounds, i.e. 15‐crown‐5, monoaza‐15‐crown‐5, and tetraazacyclotetradecane. The monomacrocycle‐substituted phthalocyanines are less soluble than the tetra‐substituted one.
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