1,3‐Addition von Aziden an Azadecaboran: 6‐Azadecaboran‐4,9‐diyltriazene | Zendy

Meyer Franc | Zendy; Paetzold Peter | Zendy; Englert Ulli | Zendy

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1,3‐Addition von Aziden an Azadecaboran: 6‐Azadecaboran‐4,9‐diyltriazene

Author(s) -

Meyer Franc,

Paetzold Peter,

Englert Ulli

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921250909

Subject(s) - chemistry , ring (chemistry) , stereochemistry , medicinal chemistry , double bond , polymer chemistry , organic chemistry

1,3‐Addition of Azides to Azadecaborane: 6‐Azadecaborane‐4,9‐diyltriazenes nido ‐NB 9 H 12 ( 1 ) reacts with azides RN 3 to form a coordinative B–N bond between B9 and N1 of RN 3 , accompanied by the α‐addition of the B4–H bond of 1 to the N3 atom of RN 3 . The products 2a, b (R = H, CH 2 Ph, respectively) thus contain an azadecaborane skeleton and a five‐membered unsaturated B 2 N 3 ring with a common B–B edge. The product 2a crystallizes in the space group Pna 2 1 .

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