Synthese von 3 H ‐1,2,3,4‐Triazametallol‐Komplexen durch Addition von Azidoameisensäure‐methylester an die Metall – Kohlenstoff‐Dreifachbindung Cyclopentadienyl‐substituierter Carbin‐Komplexe von Molybdän und Wolfram | Zendy

Stegmair Claudia M. | Zendy; Ullrich Waltraud | Zendy; Schütt Wolfgang | Zendy; Kiprof Paul | Zendy; Kreißl Fritz R. | Zendy

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Synthese von 3 H ‐1,2,3,4‐Triazametallol‐Komplexen durch Addition von Azidoameisensäure‐methylester an die Metall – Kohlenstoff‐Dreifachbindung Cyclopentadienyl‐substituierter Carbin‐Komplexe von Molybdän und Wolfram

Author(s) -

Stegmair Claudia M.,

Ullrich Waltraud,

Schütt Wolfgang,

Kiprof Paul,

Kreißl Fritz R.

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921250710

Subject(s) - chemistry , carbyne , molybdenum , cyclopentadienyl complex , triple bond , tungsten , metal , medicinal chemistry , stereochemistry , carbene , double bond , polymer chemistry , inorganic chemistry , catalysis , organic chemistry

Synthesis of 3 H ‐1,2,3,4‐Triazametallole Complexes by the Addition of Methyl Azidoformate to the Metal–Carbon Triple Bond of Cyclopentadienyl‐Substituted Carbyne Complexes of Molybdenum and Tungsten N 3 CO 2 Me attacks the electron‐rich metal–carbon triple bond in C 5 H 5 (CO) 2 ‐ n (PMe 3 ) n MCR (M = Mo, W; R = Ph, Tol; n = 0, 1) ( 1 ) to provide neutral 3 H ‐1,2,3,4‐Triazametallole complexes 2 .

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