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Alkylierung von Chinonen mit O ‐silylierten Ketenacetalen in LiClO 4 /Ether als Reaktionsmedium
Author(s) -
Ipaktschi Junes,
Heydari Akbar
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921250630
Subject(s) - chemistry , ketene , lithium perchlorate , ether , alkylation , medicinal chemistry , organic chemistry , catalysis , electrode , electrochemistry
Alkylation of Quinones by O ‐Silylated Ketene Acetals in LiClO 4 /Ether as Reaction MediumO ‐Silylated ketene acetals ( 2, 5 ) undergo 1,4‐conjugative addition to α,β‐unsaturated carbonyl systems of quinones 1 in the presence of lithium perchlorate in ether to form 2(3 H )‐benzofuranones 3

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