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Elektroreduktion organischer Verbindungen, 20 [ Darstellung von Bicyclo[ n. 1.0]alkanen durch elektrochemische Reduktion von 1,3‐Dibromcycloalkanen
Author(s) -
Hoffmann Joachim,
Voß Jürgen
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921250619
Subject(s) - chemistry , bicyclic molecule , pentane , hexane , medicinal chemistry , hydrocarbon , stereochemistry , organic chemistry
Preparation of Bicyclo[ n. 1.0]alkanes by Electrochemical Reduction of 1,3‐Dibromocycloalkanes Good yields of bicyclo[2.1.0]pentane ( 17 ) and bicyclo[3.1.0]‐hexane ( 3 ) are obtained on electroreduction of the corresponding 1,3‐dibromocycloalkanes. The results do not depend upon the stereochemistry of the starting material ( 14 vs. 15 or 11 vs. 12 ).