First evidence of unhindered silanimines obtained by flash vacuum thermolysis and vacuum gas‐solid reaction | Zendy

Denis JeanMarc | Zendy; Pellerin Zzbruno | Zendy; Guenot Pierre | Zendy; Letulle Marguerite | Zendy; Ripoll JeanLouis | Zendy

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First evidence of unhindered silanimines obtained by flash vacuum thermolysis and vacuum gas‐solid reaction

Author(s) -

Denis JeanMarc,

Pellerin Zzbruno,

Guenot Pierre,

Letulle Marguerite,

Ripoll JeanLouis

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921250615

Subject(s) - chemistry , thermal decomposition , flash vacuum pyrolysis , sous vide , yield (engineering) , flash (photography) , decomposition , isopropyl , pyrolysis , organic chemistry , thermodynamics , art , food science , visual arts , physics

The unhindered silanimines 1,1‐dimethyl‐ N ‐phenylsilanimine ( 2 ) and N ‐isopropyl‐1,1‐dimethylsilanimine ( 10 ) have been generated by flash vacuum thermolysis of the N ‐allylsilanamine 1 and vacuum gas‐solid reaction of the 1‐chlorosilanamine 9 , respectively. The silanimines 2 and 10 have been characterized by MS as well as by chemical trapping to yield 3 or dimerization to the cyclodisilazane 11 .

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