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First evidence of unhindered silanimines obtained by flash vacuum thermolysis and vacuum gas‐solid reaction
Author(s) -
Denis JeanMarc,
Pellerin Zzbruno,
Guenot Pierre,
Letulle Marguerite,
Ripoll JeanLouis
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921250615
Subject(s) - chemistry , thermal decomposition , flash vacuum pyrolysis , sous vide , yield (engineering) , flash (photography) , decomposition , isopropyl , pyrolysis , organic chemistry , thermodynamics , art , food science , visual arts , physics
The unhindered silanimines 1,1‐dimethyl‐ N ‐phenylsilanimine ( 2 ) and N ‐isopropyl‐1,1‐dimethylsilanimine ( 10 ) have been generated by flash vacuum thermolysis of the N ‐allylsilanamine 1 and vacuum gas‐solid reaction of the 1‐chlorosilanamine 9 , respectively. The silanimines 2 and 10 have been characterized by MS as well as by chemical trapping to yield 3 or dimerization to the cyclodisilazane 11 .