Synthese und Struktur von CpAlCl 2 ‐Verbindungen mit sterisch anspruchsvollen Substituenten (Cp = Me 5 C 5 , EtMe 4 C 5 ) | Zendy

Koch HansJoachim | Zendy; Schulz Stefan | Zendy; Roesky Herbert W. | Zendy; Noltemeyer Mathias | Zendy; Schmidt HansGeorg | Zendy; Heine Andreas | Zendy; HerbstIrmer Regine | Zendy; Stalke Dietmar | Zendy; Sheldrick George M. | Zendy

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Synthese und Struktur von CpAlCl 2 ‐Verbindungen mit sterisch anspruchsvollen Substituenten (Cp = Me 5 C 5 , EtMe 4 C 5 )

Author(s) -

Koch HansJoachim,

Schulz Stefan,

Roesky Herbert W.,

Noltemeyer Mathias,

Schmidt HansGeorg,

Heine Andreas,

HerbstIrmer Regine,

Stalke Dietmar,

Sheldrick George M.

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921250520

Subject(s) - chemistry , steric effects , crystal structure , x ray crystallography , stereochemistry , crystallography , physics , diffraction , optics

Synthesis and Structure of CpAlCl 2 Compounds with Sterically Demanding Substituents (Cp = Me 5 C 5 , EtMe 4 C 5 ) [1] The compounds Cp * AlCl 2 ( 3 ) (Cp * = Me 5 C 5 ) and Cp′AlCl 2 ( 4 ) (Cp′ = EtMe 4 C 5 ) have been prepared by the reaction of Cp * SiMe 3 ( 1 ) and Cp′SiMe 3 ( 2 ) with AlCl 3 . The single‐crystal X‐ray structures of 3 and 4 are reported.

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