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Synthese und Struktur von CpAlCl 2 ‐Verbindungen mit sterisch anspruchsvollen Substituenten (Cp = Me 5 C 5 , EtMe 4 C 5 )
Author(s) -
Koch HansJoachim,
Schulz Stefan,
Roesky Herbert W.,
Noltemeyer Mathias,
Schmidt HansGeorg,
Heine Andreas,
HerbstIrmer Regine,
Stalke Dietmar,
Sheldrick George M.
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921250520
Subject(s) - chemistry , steric effects , crystal structure , x ray crystallography , stereochemistry , crystallography , physics , diffraction , optics
Synthesis and Structure of CpAlCl 2 Compounds with Sterically Demanding Substituents (Cp = Me 5 C 5 , EtMe 4 C 5 ) [1] The compounds Cp * AlCl 2 ( 3 ) (Cp * = Me 5 C 5 ) and Cp′AlCl 2 ( 4 ) (Cp′ = EtMe 4 C 5 ) have been prepared by the reaction of Cp * SiMe 3 ( 1 ) and Cp′SiMe 3 ( 2 ) with AlCl 3 . The single‐crystal X‐ray structures of 3 and 4 are reported.