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Paterno‐Büchi Reaction of 2‐Morpholinoacrylonitrile with Benzil
Author(s) -
Döpp Dietrich,
Memarian Hamid Reza,
Fischer Michael Alexander,
Van Eijk Alexander M. J.,
Varma Cyril A. G. O.
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921250433
Subject(s) - benzil , oxetane , chemistry , olefin fiber , stereochemistry , polymer chemistry , organic chemistry , polymer , catalysis
In the lowest excited triplet state, benzil ( 1 ) adds highly regio‐ and stereoselectively to the olefin 2‐morpholinoacrylonitrile ( 2 ) to form solely the oxetane 5 .