Room‐Temperature C–F Bond Activation of Hexafluorobenzene by a Tailor‐Made Pt(0) Intermediate, [(dtbpm)Pt(0)] | Zendy

Hofmann Peter | Zendy; Unfried Günter | Zendy

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Room‐Temperature C–F Bond Activation of Hexafluorobenzene by a Tailor‐Made Pt(0) Intermediate, [(dtbpm)Pt(0)]

Author(s) -

Hofmann Peter,

Unfried Günter

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921250319

Subject(s) - hexafluorobenzene , chemistry , neopentane , reductive elimination , platinum , photochemistry , medicinal chemistry , stereochemistry , molecule , organic chemistry , catalysis

Reductive elimination of neopentane from cis ‐hydridoneopentyl[η 2 ‐bis(di‐ tert ‐butylphosphanyl)methane]platinum (II), (dtbpm)Pt(Np)(H) ( 1 ), allows to generate the 14‐electron fragment [(dtbpm)Pt(0)] ( 2 ) at ambient temperature. This highly reactive intermediate is capable of activating C–F bonds of hexafluorobenzene, yielding exclusively the C–F insertion product (dtbpm)Pt(C 6 F 5 )F ( 3 ).

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