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A Mass‐Spectrometric Investigation of C x NO 2 ( x =1, 2) Ions and Neutrals
Author(s) -
Sülzle Detlev,
O'Ban P. E.,
Schwarz Helmut
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921250144
Subject(s) - chemistry , mass spectrum , ion , reionization , decomposition , mass spectrometry , analytical chemistry (journal) , neutralization , spectral line , ionization , organic chemistry , physics , astronomy , chromatography , antibody , immunology , biology
The isomeric [C 2 ,N,O 2 ] + ions OCNCO + , OCCNO + , and NCCO 2 − have been generated and structurally characterized on the basis of their collisional activation, charge reversal, and neutralization‐reionization mass spectra. The open‐shell neutrals formed in the neutralization step undergo facile unimolecular decomposition. A recovery signal is obtained only for OCCNO.