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Cyclische C 6 S 6 ‐Isomere — Matrixspektroskopische und theoretische Untersuchungen
Author(s) -
Maier Günther,
Schrot Jürgen,
Reisenauer Hans Peter,
Frenking Gernot,
Jonas Volker
Publication year - 1992
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19921250142
Subject(s) - chemistry , matrix isolation , molecule , infrared , infrared spectroscopy , cis–trans isomerism , flash vacuum pyrolysis , photodissociation , pyrolysis , isomerization , matrix (chemical analysis) , computational chemistry , stereochemistry , photochemistry , organic chemistry , catalysis , physics , optics , chromatography
Cyclic C 6 S 6 Isomers — Matrix‐Spectroscopic and Theoretical Investigations A yellow C 6 S 6 isomer, which can be interconverted photo‐chemically into a colorless second C 6 S 6 isomer, may be obtained upon matrix photolysis and flash pyrolysis of the precursor molecule 7 . The structures of these isomers are most likely 3 and 5 , as shown by comparison of their experimental with the calculated infrared spectra of the five possible cyclic C 6 S 6 isomers 1 — 5 .