Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN 4 ‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten | Zendy

Herrmann Wolfgang A. | Zendy; Huber Norbert W. | Zendy; Härter Peter | Zendy; Denk Michael | Zendy; Dyckhoff Florian | Zendy

Premium

Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN 4 ‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten

Author(s) -

Herrmann Wolfgang A.,

Huber Norbert W.,

Härter Peter,

Denk Michael,

Dyckhoff Florian

Publication year - 1992

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19921250119

Subject(s) - chemistry , tantalum , niobium , transition metal , amide , lithium (medication) , medicinal chemistry , metal , stereochemistry , organic chemistry , catalysis , medicine , endocrinology

Multiple Bonds between Main‐Group Elements and Transition Metals, CII [1] . — Volatile MN 4 Metal Complexes of Niobium and Tantalum Containing Dimethylsilyl Substituents Niobium and tantalum complexes 4a and 4b of formula (Me 2 SiH)N=M[N(SiHMe 2 ) 2 ] 3 ( a : M=Nb; b : M=Ta) are formed from lithium bis(dimethylsilyl)amide and either MOCl 3 ( 2a , b ) or MCl 5 ( 3a , b ). No β‐hydrogen decomposition of these compounds occurs under normal conditions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research