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Carbonyl(η 5 ‐cyclopentadienyl)(trimethylphosphan)[η 2 ‐(methylthio)‐phenylcarben]molybdän‐tetrafluoroborat – ein amphiphiler Carbenkomplex
Author(s) -
Kreißl Fritz R.,
Stegmair Claudia M.
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911241217
Subject(s) - chemistry , cyclopentadienyl complex , carbene , tetrafluoroborate , electrophile , medicinal chemistry , nucleophile , molybdenum , stereochemistry , organic chemistry , ionic liquid , catalysis
Carbonyl(η 5 ‐cyclopentadienyl)(trimethylphosphane)[η 2 ‐(methylthio)phenylcarbene]molybdenum Tetrafluoroborate – an Amphiphilic Carbene Complex The title complex 1 adds the electrophile SMe + as well as the nucleophilic PMe 3 at the carbene carbon to form the complexes 2 and 3 , respectively.
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