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Wasserstoffübertragungen, 18 Zur cis ‐Selektivität bei der Dehydrierung mit Chinonen
Author(s) -
Wehage Hubert,
Heesing Albert
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911241138
Subject(s) - chemistry , dehydrogenation , medicinal chemistry , selectivity , pyrolytic carbon , catalysis , organic chemistry , pyrolysis
Hydrogen Transfer Reactions, 18 1) . — The cis Selectivity in Dehydrogenation by Quinones In contrast to literature results the dehydrogenation of [ cis ‐ 5,6‐D 2 ]‐1,3‐cyclohexadiene by o ‐chloranile proceeds stereo‐selectively. Fast 1,5‐hydrogen shifts in the last pyrolytic step of the synthesis are the cause of the contrary report.