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Metallkomplexe mit biologisch wichtigen Liganden, LXIII Aspartam als dreizähniger Ligand in metallorganischen Komplexen: Darstellung und Struktur von Cp * Rh[O 2 CCH 2 CH(NH 2 )C(O)NCH(CH 2 Ph)CO 2 Me]
Author(s) -
Krämer Roland,
Polborn Kurt,
Beck Wolfgang
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911241109
Subject(s) - chemistry , deprotonation , ligand (biochemistry) , stereochemistry , dipeptide , medicinal chemistry , metal , aspartame , organic chemistry , receptor , amino acid , ion , biochemistry
Metal Complexes of Biologically Important Ligands, LXIII 1) . — Aspartame as Tridendate Ligand in Organometallic Complexes: Preparation and Structure of Cp * Rh[O 2 CCH 2 CH(NH 2 )C(O)NCH(CH 2 Ph)CO 2 Me] Aspartame reacts with [Cp * RhCl 2 ] 2 in the presence of base to give the title complex 1 with the deprotonated tridendate dipeptide ester as ligand.