Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, XCVI Niob‐ und Tantalkomplexe mit Imido‐Liganden | Zendy

Herrmann Wolfgang A. | Zendy; Denk Michael | Zendy; Dyckhoff Florian | Zendy; Behm Joachim | Zendy

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Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, XCVI Niob‐ und Tantalkomplexe mit Imido‐Liganden

Author(s) -

Herrmann Wolfgang A.,

Denk Michael,

Dyckhoff Florian,

Behm Joachim

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911241104

Subject(s) - chemistry , tantalum , niobium , amide , yield (engineering) , lithium amide , transition metal , lithium (medication) , medicinal chemistry , stereochemistry , catalysis , organic chemistry , metallurgy , medicine , materials science , endocrinology , enantioselective synthesis

Multiple Bonds Between Main‐Group Elements and Transition Metals, XCVI. – Niobium and Tantalum Complexes Having Imido Ligands The new niobium and tantalum complexes 2b and 2c of formula M[N(SiMe 3 ) 2 ] 2 (NSiMe 3 )(OSiMe 3 ) (M = Nb, b ; Ta, c) are accessible by the reaction of the oxychlorides MOCl 3 with the lithium amide LiN[Si(CH 3 ) 3 ] 2 in 36 and 27% isolated yield, respectively.

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