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Mit Donorzentren versehener korbförmiger Molekülhohlraum — Darstellung, Struktur, Eigenschaften
Author(s) -
Breitenbach Jörg,
Rissanen Kari,
Wolf Ute U.,
Vögtle Fritz
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911241027
Subject(s) - chemistry , crystal structure , molecule , pyridine , stereochemistry , crystallography , polymer chemistry , organic chemistry
Basket‐shaped Molecular Cavity‐Containing Donor Centres — Synthesis, Structure, Properties The macrocyclic basket‐shaped molecule 2 , composed of three 4‐donor‐substituted pyridine units, is synthesized by cyclisation of the chloromethyl compound 7 with sulfonamide 8 . The X‐ray structure analysis of 2 gives an impression of the shape of the molecular basket. Furthermore it demonstrates that the toluenesulfonamide residues interlink, creating dimeric units of 2 in the crystal.