Mehrstufige reversible Redoxsysteme, LVI. Kristallstruktur und Leitfähigkeiten der CT‐Komplexe TTF/2‐X‐5‐Me‐DCNQI (X = Cl, Br, I) aus Tetrathiafulvalen und 2‐Halogen‐ N,N′ ‐dicyan‐5‐methyl‐1,4‐benzochinondiimin | Zendy

Erk Peter | Zendy; Hünig Siegfried | Zendy; Klebe Gerhard | Zendy; Krebs Martin | Zendy; Schütz Jost Ulrich Von | Zendy

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Mehrstufige reversible Redoxsysteme, LVI. Kristallstruktur und Leitfähigkeiten der CT‐Komplexe TTF/2‐X‐5‐Me‐DCNQI (X = Cl, Br, I) aus Tetrathiafulvalen und 2‐Halogen‐ N,N′ ‐dicyan‐5‐methyl‐1,4‐benzochinondiimin

Author(s) -

Erk Peter,

Hünig Siegfried,

Klebe Gerhard,

Krebs Martin,

Schütz Jost Ulrich Von

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240921

Subject(s) - chemistry , tetrathiafulvalene , crystallography , crystal structure , molecule , halogen , single crystal , stereochemistry , alkyl , organic chemistry

Multi‐Step Redox Systems, LVI. – Crystal Structures and Conductivities of the CT Complexes TTF/2‐X‐5‐Me‐DCNQI (X = Cl, Br, I) from Tetrathiafulvalene and 2‐Halogeno‐ N,N′ ‐dicyano‐5‐methyl‐1,4‐benzoquinone Diimine In contrast to microcrystalline powders single crystals of the title complexes show low conductivities (&10; < sigma ‐5 Scm ‐1 ). These properties are based on a peculiar mixed stack arrangement of donor and acceptor molecules within the crystal lattice (space group P2 1 / n ).

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