Reaktionen von Komplexliganden, XLIII. Optisch aktive Aminocarben‐Komplexe: Reagentien für die regiospezifische und diastereoselektive Synthese von γ‐Lactamen | Zendy

Dötz Karl Heinz | Zendy; Weber Rita | Zendy

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Reaktionen von Komplexliganden, XLIII. Optisch aktive Aminocarben‐Komplexe: Reagentien für die regiospezifische und diastereoselektive Synthese von γ‐Lactamen

Author(s) -

Dötz Karl Heinz,

Weber Rita

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240726

Subject(s) - chemistry , aminolysis , optically active , reagent , carbene , stereochemistry , medicinal chemistry , organic chemistry , catalysis

Reactions of Complex Ligands, XLIII. ‐ Optically Active Aminocarbene Complexes: Reagents for the Regiospecific and Diastereoselective Synthesis of γ‐Lactams Optically active pentacarbonyl[amino(aryl)carbene] complexes 2 ‐ 5 of chromium have been obtained by aminolysis of methoxycarbene complexes 1 with L‐amino acid esters. The alanyl and phenylalanyl compounds 2, 3 react with 1‐octyne regiospecifically and moderately diastereoselectively to give the pyrrolinones 6 , 7 .

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