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Asymmetrische Synthese chiraler Phosphorverbindungen durch destruktiv‐Oxidation von P(III)‐Verbindungen mittels chiraler Oxaziridine
Author(s) -
Verfürth Uwe,
Ugi Ivar
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240725
Subject(s) - chemistry , camphor , stereoselectivity , oxaziridine , enantioselective synthesis , reagent , medicinal chemistry , stereochemistry , organic chemistry , catalysis
Asymmetric Synthesis of Chiral Phosphorus Compounds by Destructive‐Selective Oxidation of P(III) Compounds by Means of Chiral Oxaziridines From camphor and fenchone chiral N ‐sulfonyloxaziridines (e.g, 7 , 13 ) are available that are well‐suited for the destructive‐stereoselective oxidation of P(III) compounds 16 . Optimum reagents and reaction conditions for this oxidation are determined by a systematic study. Chiral P(III) and P(V) compounds can thus be prepared from racemic P(III) derivatives.