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Redox Properties of Diphosphanes
Author(s) -
Niemann Jürgen,
Schoeller Wolfgang W.,
von der Gönna Volker,
Niecke Edgar
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240713
Subject(s) - dication , chemistry , redox , electrochemistry , radical ion , medicinal chemistry , polymer chemistry , organic chemistry , ion , electrode
Diphosphanes undergo electrochemical one‐electron oxidation. In case amino groups are at the phosphorus, the resulting distonic diphosphane radical cations disproportionate readily into a dication and a diphosphane; the former separates into two phosphenium cations.
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