On the Generation of Polycarbon Nitride Radicals C  n  N .  ( n  = 2–5) by Neutralization‐Reionization Mass Spectrometry | Zendy

Sülzle Detlev | Zendy; Seemayer Katrin | Zendy; Schwarz Helmut | Zendy; Witulski Bernhard | Zendy; Hopf Henning | Zendy

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On the Generation of Polycarbon Nitride Radicals C n N . ( n = 2–5) by Neutralization‐Reionization Mass Spectrometry

Author(s) -

Sülzle Detlev,

Seemayer Katrin,

Schwarz Helmut,

Witulski Bernhard,

Hopf Henning

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240625

Subject(s) - chemistry , mass spectrometry , radical , reionization , dissociation (chemistry) , collision induced dissociation , tandem mass spectrometry , neutralization , molecule , photochemistry , ion , organic chemistry , ionization , chromatography , antibody , immunology , biology

The title radicals, thought to be of prime importance in the genesis of interstellar organic molecules, are accessible in the gas phase by neutralization of the corresponding C n N + ions ( n = 2–5) using tandem mass spectrometry methods (neutralization‐reionization mass spectrometry). Collision‐induced dissociation reactions of mass‐selected C n N + are in keeping with the connectivity of a “carbon rod” bearing a nitrogen atom at one terminus.

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