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Die Synthese von Chlor(trichlormethyl)sulfin, Cl 3 C(Cl)CSO
Author(s) -
Maletzo Christian,
Sundermeyer Wolfgang
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240551
Subject(s) - chemistry , adduct , anthracene , medicinal chemistry , yield (engineering) , thermal decomposition , chloride , stereochemistry , organic chemistry , metallurgy , materials science
Synthesis of Chloro(trichloromethyl)sulfine, Cl 3 C(Cl)CSO The unstable trichlorothioacetyl chloride ( 2 ) could be trapped by a Diels‐Alder reaction with anthracene to form the adduct 3 , which in turn could be oxidized to the corresponding sulfine adduct 4 . Finnaly, chloro(trichloromethyl)sulfine ( 5 ) was prepared in good yield by vacuum thermolysis (retro Diels‐Alder reaction) of 4 .
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