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Darstellung und Struktur von Thallium(I)‐2,4,6‐tris(trifluormethyl)thiophenolat, einer Verbindung mit faltblattartig‐polymerem Aufbau
Author(s) -
Labahn Dieter,
Phol Ehmke,
HerbstIrmer Regine,
Stalke Dietmar,
Roesky Herbert W.,
Sheldrick George M.
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240522
Subject(s) - chemistry , thallium , trifluoromethyl , tris , crystal structure , molecule , crystallography , stereochemistry , medicinal chemistry , inorganic chemistry , organic chemistry , biochemistry , alkyl
Preparation and Structure of Thallium(I) 2,4,6‐Tris(trifluoromethyl thiophenolate, a Compound with a Folded Polymeric Structure The title compound, thallium(I) 2,4,6‐tris(trifluoromethyl)thiophenolate (1) has been prepared by using either TlOEt and (CF 3 ) 3 C 6 H 2 SH or Tl 2 CO 3 and (CF 3 ) 3 C 6 H 2 SNa. A single X‐ray structural analysis shows a folded polymeric structure for 1 ; the crystal lattice incorporates half of a 1,4‐dioxane molecule per Tl atom. This compound has a surprisingly high kinetic stability compared to known thallium(I) thiolates.