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Undecacarbonyl(μ 2 ‐trifluoromethyl isocyanide)triruthenium, a Derivative of [Ru 3 (CO) 12 ] with [Fe 3 (CO) 12 ] Structure
Author(s) -
Lentz Dieter,
Marschall Robert,
Hahn Ekkehardt
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240418
Subject(s) - chemistry , isocyanide , crystal structure , ruthenium , trifluoromethyl , derivative (finance) , crystallography , x ray crystallography , medicinal chemistry , catalysis , organic chemistry , diffraction , alkyl , financial economics , economics , physics , optics
[Ru 3 (CO) 10 (μ 2 ‐CO)(μ 2 ‐CNCF 3 )] ( 1 ), [Ru 3 (CO) 10 (CNCF 3 ) 2 ] ( 2 ), and [Ru 2 (CO) 6 (μ 2 ‐CNCF 3 ) 3 ] ( 3 ) are obtained by the reaction of [Ru 3 (CO) 11 (CH 3 CN)] with CNCF 3 . An X‐ray crystal structure determination revealed, that 1 has an unusual [Fe 3 (CO) 12 ] structure, different from most other derivatives of [Ru 3 (CO) 12 ].