Undecacarbonyl(μ 2 ‐trifluoromethyl isocyanide)triruthenium, a Derivative of [Ru 3 (CO) 12 ] with [Fe 3 (CO) 12 ] Structure | Zendy

Lentz Dieter | Zendy; Marschall Robert | Zendy; Hahn Ekkehardt | Zendy

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Undecacarbonyl(μ 2 ‐trifluoromethyl isocyanide)triruthenium, a Derivative of [Ru 3 (CO) 12 ] with [Fe 3 (CO) 12 ] Structure

Author(s) -

Lentz Dieter,

Marschall Robert,

Hahn Ekkehardt

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240418

Subject(s) - chemistry , isocyanide , crystal structure , ruthenium , trifluoromethyl , derivative (finance) , crystallography , x ray crystallography , medicinal chemistry , catalysis , organic chemistry , diffraction , alkyl , financial economics , economics , physics , optics

[Ru 3 (CO) 10 (μ 2 ‐CO)(μ 2 ‐CNCF 3 )] ( 1 ), [Ru 3 (CO) 10 (CNCF 3 ) 2 ] ( 2 ), and [Ru 2 (CO) 6 (μ 2 ‐CNCF 3 ) 3 ] ( 3 ) are obtained by the reaction of [Ru 3 (CO) 11 (CH 3 CN)] with CNCF 3 . An X‐ray crystal structure determination revealed, that 1 has an unusual [Fe 3 (CO) 12 ] structure, different from most other derivatives of [Ru 3 (CO) 12 ].

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