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The Azo/Nitrene Route to cis,cis ‐Trialkyltriaziridines, 1 Synthesis of syn ‐Azo Azides of Defined Proximity
Author(s) -
Marterer Wolfgang,
Klingler Otmar,
Thiergardt Regina,
Knothe Lothar,
Prinzbach Horst
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240329
Subject(s) - nitrene , chemistry , azide , nitrogen atom , stereochemistry , nitrogen , polymer chemistry , medicinal chemistry , photochemistry , organic chemistry , catalysis , group (periodic table)
Bi‐ and polycyclic syn ‐azo azide substrates H, 5, 14 and I, 15 – 18, 36, 41d , respectively, of varying rigidity and proximity (with the potential nitrene nitrogen atom in the π plane of the azo function) are prepared in order to synthesize kinetically stabilized cis,cis ‐trialkyltriaziridines.