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Darstellung von [Dimethylamino(thiocarbonyl)thioamido]titan(IV)‐dihalogeniden – Verbindungen mit kurzen Ti – N‐Bindungen
Author(s) -
MellerRehbein Birgit,
Roesky Herbert W.,
Noltemeyer Mathias
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240318
Subject(s) - chemistry , adduct , pyridine , medicinal chemistry , titanium , titan (rocket family) , organic chemistry , engineering , aerospace engineering
Preparation of [Dimethylamino(thiocarbonyl)thioamido]titanium(IV) Dihalides – Compounds with Short Ti – N Bonds Reaction of Me 2 NC(S)SN(SiMe 3 ) 2 ( 1 ) with TiCl 4 and TiBr 4 yields ( 2 ) and ( 3 ). Treatment of 2 and 3 with pyridine (py) leads to the solvates · 3 py [ 2a (XCl), 3a (XBr)]. These adducts have been characterized by X‐ray structure determination.