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Über die Funktion von Di( tert ‐butyl)silandiolat als Anker für Metallfragmente in hohen und mittleren Oxidationsstufen. Synthese und Strukturen von ( t Bu 2 SiO 2 (TeCl 2 –μ‐Cl 2 – TeCl 2 ) und ( t Bu) 2 Si(OReO 3 ) 2
Author(s) -
Roesky Herbert W.,
Mazzah Ahmed,
Hesse Detlev,
Noltemeyer Mathias
Publication year - 1991
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19911240317
Subject(s) - chemistry , crystallography , stereochemistry
Function of Di( tert ‐butyl)silanediolate as an Anchor for Metal Fragments in High and Medium Oxidation States. Synthesis and Structures of ( t Bu) 2 SiO 2 (TeCl 2 – μ‐Cl 2 – TeCl 2 ) and ( t Bu) 2 Si(OReO 3) ) 2 The compounds ( t Bu) 2 SiO 2 (TeCl 2 – μ‐Cl 2 – TeCl 2 ) ( 2 ) and ( t Bu) 2 Si(OReO 3 ) 2 ( 3 ) have been prepared by the reactions of ( t Bu) 2 Si(OH) 2 ( 1 ) with TeCl 4 and Re 2O7 . The single‐crystal X‐ray structures of 2 and 3 are reported. The ( t Bu) 2 SiO 2 group functions as an anchor for the metal fragments TeCl 3 and ReO 3 .