Steuerung der Aggregation von Mangankomplexen durch unterschiedliche Basen an den Beispielen [Mn(O 2 CCF 3 ) 2 (py) 4 ] und [Mn 3 (O 2 CCF 3 ) 6 (benz) 6 ] | Zendy

Hübner Kay | Zendy; Roesky Herbert W. | Zendy; Noltemeyer Mathias | Zendy; Bohra Rakesh | Zendy

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Steuerung der Aggregation von Mangankomplexen durch unterschiedliche Basen an den Beispielen [Mn(O 2 CCF 3 ) 2 (py) 4 ] und [Mn 3 (O 2 CCF 3 ) 6 (benz) 6 ]

Author(s) -

Hübner Kay,

Roesky Herbert W.,

Noltemeyer Mathias,

Bohra Rakesh

Publication year - 1991

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19911240316

Subject(s) - chemistry , manganese , benzonitrile , pyridine , trifluoroacetic acid , yield (engineering) , medicinal chemistry , organic chemistry , materials science , metallurgy

Influencing the Aggregation of Manganese Complexes by Different Bases: Formation of [Mn(O 2 CCF 3 ) 2 (py) 4 ] and [Mn 3 (O 2 CCF 3 ) 6 (benz) 6 ] Manganese powder reacts quantitatively with trifluoroacetic acid to yield Mn(O 2 CCF 3 ) 2 ( 1 ). The aggregation of 1 is directed by different N‐containing bases. Pyridine (py) forms the mono‐nuclear complex [Mn(O 2 CCF 3 ) 2 (py) 4 ] ( 2 ), while benzonitrile (benz) yields the trinuclear complex [Mn 3 (O 2 CCF 3 ) 6 (benz) 6 ] ( 3 ). The X‐ray structures of 2 and 3 are described.

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